VAN WATERS AND ROGERS INC/SUB OF UNIVAR -- FREON TF & PCA  -- 6850-00-681-5688
<pre>=====================  Product Identification  =====================

Product ID:FREON TF & PCA
MSDS Date:02/05/1993
FSC:6850
NIIN:00-681-5688
MSDS Number: BTHNJ
=== Responsible Party ===
Company Name:VAN WATERS AND ROGERS INC/SUB OF UNIVAR
Address:6100 CARILLON PT
City:KIRKLAND
State:WA
ZIP:98033
Country:US
Info Phone Num:206-889-3712
Emergency Phone Num:206-889-3712
CAGE:0STM5
=== Contractor Identification ===
Company Name:VOPAK USA INC
Address:6100 CARILLON POINT
Box:City:KIRKLAND
State:WA
ZIP:98033-7357
Country:US
Phone:425-889-3400/425-889-3617
CAGE:0STM5

=============  Composition/Information on Ingredients  =============

Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113)  (SARA
    III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 100% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000PPM
ACGIH TLV:1000PPM/1250STEL9394
Ozone Depleting Chemical:1

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50 = 43000 MG/KG (RATS)
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:SKIN IRRITATION DUE TO RAPID
    EVAPORATION WITH POSSIBLE DISCOMFORT OR RASH. PROLONGED SKIN
    CONTACT MAY CAUSE TEMPORARY TINGLING. MAY CAUSE MILD EYE
    IRRITATION. ASPIRATION HAZARD. INHALATION MAY CAUSE T EMPORARY
    NERVOUS SYSTEM DEPRESSION WITHANAESTHETIC EFFECTS, ALTERATION OF
    HEART'S ELECTRICAL ACTIVITY.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
    CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:SKIN IRRITATION, NUMBNESS, COLDNESS, DRYING;
    EYE IRRITATION, DISCOMFORT, BLURRING, TEARING; CHEMICAL PNEUMONIA
    WITH COUGHING, GASPING, CHOKING, SHORTNESS OF BREATH, BLUSIH
    DISCOLORATION OF SKIN; DIZZI NESS, HEADACHE, CONFUSION,
    INCOORDINATION, LOSS OF CONSCIOUSNESS, IRREGULAR PULSE,
    PALPITATIONS, INADEQUATE CIRCULATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
    WARM AND QUIET. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA
    THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL
    ATTENTION.	EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.
    GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IF
    VOMITING OCCURS, KEEP HEAD BELOW HIPS. CONSULT PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Flash Point:NONFLAMMABLE
Autoignition Temp:Autoignition Temp Text:572F
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING
    FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
    FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
    SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY POSE
    ASPHYXIATION HAZARD. DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
    DECOMPOSITION MAY OCCUR.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS.
    CONTAIN SPILL. COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL
    DRUMS FOR RECOVERY OR DISPOSAL. USE SCBA FOR LARGE SPILLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN A CLEAN, DRY AREA. DO NOT
    HEAT ABOVE 125F.
Other Precautions:PRODUCT POSES A HAZRD OF FATAL HEART IRREGULARITIES
    IF INHLAED AT HIGH CONCENTRATONS. SKIN OR EYE CONTACT MAY CAUSE
    IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE DRYING OF THE SKIN.
    AVOID CONTACT.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:UNDER NORMAL CONDITIONS OF USE, NO RESPIRATORY
    PROTECTION IS REQUIRED WHEN USING THIS PRODUCT. SELF-CONTAINED
    BREATHING APPARATUS IS REQUIRED IF A LARGE SPILL OCCURS.
Ventilation:NORAML VENTILATION IS GENERALLY ADEQUATE. LOCAL EXHAUST
    SHOULD BE USED WHEN LARGE QUANTITIES ARE RELEASED.
Protective Gloves:IMPERVIOUS GLOVES RECOMMENDED.
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EMERGENCY EYEWASH STATION AND SHOWER SHOULD
    BE AVAILABLE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
    AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
NOTES TO PHYSICIAN: ACTIVATED CHARCOAL SLURRY MAY BE ADMINISTERED.
    BECAUSE OF INCREASED RISK OF ELICITING CARDIAC DYSRHYTHMIAS,
    CATACHOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD BE USED WITH
    SPECIAL CA UTION IN SITUATIONS OF EMERGENCY LIFE SUPPORT. DUE TO
    DANGER OF ASPIRATION, EMESIS/GASTRIC LAVAGE SHOULD NOT BE USED.

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:6.46 PSIA
Vapor Density:2.9
Spec Gravity:1.57
pH:7
Evaporation Rate &amp; Reference:> 1 (CCL4 = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ETHEREAL ODOR
Percent Volatiles by Volume:100 %

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
ALKALI, ALKALLINE EARTH METALS (POWDERED AL, ZN, BE, ETC).
Stability Condition to Avoid:OPEN FLAMES, HIGH TEMPERATURES ( ABOVE
    125F)
Hazardous Decomposition Products:HYDROCHLORIC AND HYDROFLUORIC ACIDS,
    POSSIBLY CARBONYL HALIDES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
    ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
    LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

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